Preparation and Characterization of the Phthalazinone Structure-based Microporous Organic Polymer

DOI

10.2991/mebe-15.2015.200How to use a DOI?

Keywords

Phthalazinone; Triazine; Microporous

Abstract

In this work, a new covalent triazine framework based on phthalazinone-containing dinitrile building blocks was prepared by the dynamic nitrile-trimerization reaction. The FT-IR spectra of BCTF illustrated the characteristic peaks of the triazine at 1503 cm-1 and 1360 cm-1. The nitrogen sorption isotherm (Type-I) showed a rapid uptake at low pressure (0-0.1bar) indicating a permanent microporous nature. Pore size distribution lower than 2nm was calculated using nonlocal density functional theory (NL-DFT). TGA results showed that BCTF polymer with the skeleton decomposition temperature above 500 had relatively excellent thermal stability.

Copyright

© 2015, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Kuanyu Yuan
AU  - Cheng Liu
AU  - Hongmin Duan
AU  - Manxia Zhang
AU  - Xigao Jian
PY  - 2015/04
DA  - 2015/04
TI  - Preparation and Characterization of the Phthalazinone Structure-based Microporous Organic Polymer
BT  - Proceedings of the 2015 International Conference on Materials, Environmental and Biological Engineering
PB  - Atlantis Press
SP  - 894
EP  - 897
SN  - 2352-5401
UR  - https://doi.org/10.2991/mebe-15.2015.200
DO  - 10.2991/mebe-15.2015.200
ID  - Yuan2015/04
ER  -