Synthesis and Crystal Structures of a mixed-metal Complex with Nitrilotriacetamides
Authors
Guichun Sun, Jingwen Ran
Corresponding Author
Guichun Sun
Available Online April 2017.
- DOI
- 10.2991/icmse-17.2017.44How to use a DOI?
- Keywords
- crystal structure, nitrilotriacetamide, mixed-metal complex
- Abstract
A novel complex with nitrilotriacetamides(L) has been synthesized. Single-crystal X-ray diffraction analysis determined the molecular formula as C12H28N8Na2NiO10. The crystal belongs to the triclinic system with P-1 space group. In this molecule, the L ion exhibits an infrequent coordination mode. The nickel center is hexa-coordinated to a slightly distorted octahedral configuration by six nitrogen atoms from two L ligands. The sodium ion is six-coordinated with three oxygen atoms of ligands and three oxygen atoms of water molecules. Two water molecules bridge two Na+ ions.
- Copyright
- © 2017, the Authors. Published by Atlantis Press.
- Open Access
- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - Guichun Sun AU - Jingwen Ran PY - 2017/04 DA - 2017/04 TI - Synthesis and Crystal Structures of a mixed-metal Complex with Nitrilotriacetamides BT - Proceedings of the 2017 7th International Conference on Manufacturing Science and Engineering (ICMSE 2017) PB - Atlantis Press SP - 245 EP - 249 SN - 2352-5401 UR - https://doi.org/10.2991/icmse-17.2017.44 DO - 10.2991/icmse-17.2017.44 ID - Sun2017/04 ER -