Tetra-cobalt-substiituted Dimeric Tungstoantimonate: Na10[Co4(H2O)10(B- -SbW9O33)2]•36H2O

DOI

10.2991/icaemt-15.2015.133How to use a DOI?

Keywords

Polyoxometalate (POM), Cobalt, Substitute

Abstract

A new tetra-cobalt-substiituted dimeric tungstoantimonate Na10[Co4(H2O)10(B- -SbW9- O33)2]•36H2O 1 was synthesized in a weakly alkaline solution. The compound was characterized by elemental analysis and IR spectroscopy. A single-crystal X-ray analysis was carried out on the crystal 1 which crystallizes in monoclinic system, space group P 21/n, with a = 12.529 Å, b = 12.778 Å, c = 29.434 Å, = 90.000º, = 101.158º , = 90.000º and Z = 2. Polyanion 1 consists of two B- -SbW9 units which are linked by four cobalt ions leading to a Keggin-type tetra-cobalt-substiituted dimeric structure.

Copyright

© 2015, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Rongxin Tan
AU  - Tongxin Xiao
AU  - Jin Wang
AU  - Pingping Zhao
PY  - 2015/08
DA  - 2015/08
TI  - Tetra-cobalt-substiituted Dimeric Tungstoantimonate: Na10[Co4(H2O)10(B- -SbW9O33)2]•36H2O
BT  - Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology
PB  - Atlantis Press
SP  - 700
EP  - 703
SN  - 2352-5401
UR  - https://doi.org/10.2991/icaemt-15.2015.133
DO  - 10.2991/icaemt-15.2015.133
ID  - Tan2015/08
ER  -