Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology

Flame retardancy and thermal degradation mechanism of epoxy resins composites based on a PEPA-substituted polyphosphoramide

Authors
Wei Zhao, Jiping Liu
Corresponding Author
Wei Zhao
Available Online August 2015.
DOI
10.2991/icaemt-15.2015.111How to use a DOI?
Keywords
polyphosphoramide, epoxy resins, flame retardant, thermal stability.
Abstract

A series of flame retardant epoxy resin composites with different content of PEPA-substituted polyphosphoramide (PSA) were prepared. The flame retardancy of EP/PSA composites was evaluated by UL-94 vertical burning test and the pyrolysis combustion flow calorimetry (PCFC). With the incorporation of 20 wt% PSA, the EP/PSA composites could reach the UL-94 V-0 rating and remarkable reduction of heat release rate could be observed. The thermal degradation mechanisms of the EP/PSA composites were investigated by Fourier transform infrared spectra (FTIR). FTIR analysis indicated that PSA could catalysis the decomposition of EP at lower temperature. The thermal degradation kinetics results of EP and EP/PSA composites by the Kissinger method showed that the apparent activation energy (Ea) reduced with incorporation of PSA, which indicated PSA could efficiently catalysis and promote the char forming process of EP.

Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology
Series
Advances in Engineering Research
Publication Date
August 2015
ISBN
978-94-6252-108-7
ISSN
2352-5401
DOI
10.2991/icaemt-15.2015.111How to use a DOI?
Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Wei Zhao
AU  - Jiping Liu
PY  - 2015/08
DA  - 2015/08
TI  - Flame retardancy and thermal degradation mechanism of epoxy resins composites based on a PEPA-substituted polyphosphoramide
BT  - Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology
PB  - Atlantis Press
SP  - 578
EP  - 582
SN  - 2352-5401
UR  - https://doi.org/10.2991/icaemt-15.2015.111
DO  - 10.2991/icaemt-15.2015.111
ID  - Zhao2015/08
ER  -